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Chemical order and crystallographic texture of FePd:Cu thin alloy films

机译:Fepd:Cu薄合金薄膜的化学顺序和晶体结构

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摘要

FePd thin films have been recently considered as promising material forhigh-density magnetic storage devices. However, it is necessary to find aproper method of fabrication for the (001)-textured and chemically well-orderedalloy. In this paper, we present the detailed investigations of latticeparameters, chemical order degree, grain sizes and crystallographic texture,carried out on FePd alloys with 10 at.% of Cu addition. The initial [Cu(0.2nm)/Fe(0.9 nm)/Pd(1.1 nm)]x5 multilayers were thermally evaporated in anultra-high vacuum on MgO(100), Si(100), Si(111) and Si(100) covered by 100 nmthick layer of amorphous SiO2. In order to obtain homogeneous FePd:Cu alloy,the multilayers were annealed in two different ways. First, the samples wererapidly annealed in nitrogen atmosphere at 600oC for 90 seconds. Next, the longannealing in a high vacuum for 1 hour at 700oC was done. This paper focuses onquantitative investigations of the chemical order degree and crystallographictexture of ternary FePd:Cu alloys deposited on four different substrates. Inorder to obtain both quantities we have taken a novel approach to consider theproblem of dopant atoms located in the FePd structure. The studies of thestructure were done using X-Ray Diffraction (XRD) performed with synchrotronradiation and pole figures measurements. We have found that the addition of Cuchanges the FePd lattice parameters and lattice distortion. We have also shown,that using different substrates it is possible to obtain a FePd:Cu alloy withdifferent chemical order and texture. Moreover, it was observed that texturecategory is substrate dependent.
机译:FePd薄膜最近被认为是用于高密度磁存储设备的有前途的材料。但是,有必要找到一种适当的制造方法,以制造(001)织构化且化学上有序的合金。本文中,我们对添加了10 at。%Cu的FePd合金进行了晶格参数,化学有序度,晶粒尺寸和晶体织构的详细研究。最初的[Cu(0.2nm)/ Fe(0.9nm)/ Pd(1.1nm)] x5多层膜在超高真空下在MgO(100),Si(100),Si(111)和Si(100)上热蒸发)被100 nm厚的非晶SiO2层覆盖。为了获得均质的FePd:Cu合金,以两种不同的方式对多层进行退火。首先,将样品在氮气气氛中于600oC迅速退火90秒。接下来,在700°C的高真空下进行了1小时的长时间退火。本文重点研究了沉积在四种不同基底上的三元FePd:Cu合金的化学有序度和晶体织构的定量研究。为了获得两个量,我们采取了一种新颖的方法来考虑位于FePd结构中的掺杂原子的问题。使用同步辐射和极图测量的X射线衍射(XRD)对结构进行了研究。我们发现,添加铜会改变FePd晶格参数和晶格畸变。我们还表明,使用不同的基材可以获得具有不同化学顺序和织构的FePd:Cu合金。此外,观察到纹理类别是底物依赖性的。

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